Alcohols, Phenols, and Ethers: Important Questions for NEET - Study24x7
Social learning Network

Alcohols, Phenols, and Ethers: Important Questions for NEET

Updated on 03 September 2024
study24x7
Study24x7
29 min read 4 views
Updated on 03 September 2024

Alcohols, Phenols, and Ethers


Alcohols, phenols, and ethers are fundamental organic compounds that play a crucial role in various chemical reactions and industrial applications. In the NEET exam, these topics are frequently tested due to their significance in organic chemistry. Understanding their properties, reactions, and applications can help students tackle related questions effectively. This article provides an overview of important questions on alcohols, phenols, and ethers, which are essential for NEET preparation.

Section 1: Understanding Alcohols

Alcohols are organic compounds characterized by the presence of one or more hydroxyl (-OH) groups attached to a carbon atom. Based on the number of hydroxyl groups, alcohols can be classified as monohydric, dihydric, and polyhydric. They can further be classified as primary (1°), secondary (2°), or tertiary (3°) alcohols based on the carbon to which the hydroxyl group is attached.

Key Concepts and Reactions

  1. Preparation of Alcohols
  2. Hydration of Alkenes: This involves adding water to alkenes in the presence of an acid catalyst to form alcohols.
  3. Hydroboration-Oxidation: Involves the addition of BH3 (borane) to an alkene, followed by oxidation with H2O2 to form an alcohol.
  4. Reduction of Carbonyl Compounds: Aldehydes and ketones can be reduced to primary and secondary alcohols, respectively, using reducing agents like NaBH4 or LiAlH4.
  5. Physical Properties of Alcohols
  6. Discuss the boiling points, solubility in water, and hydrogen bonding in alcohols. Generally, alcohols have higher boiling points than their corresponding hydrocarbons due to hydrogen bonding.
  7. Chemical Reactions of Alcohols
  8. Dehydration: Alcohols undergo dehydration in the presence of strong acids to form alkenes. This reaction follows the Zaitsev’s rule.
  9. Oxidation: Primary alcohols are oxidized to aldehydes and further to carboxylic acids, while secondary alcohols are oxidized to ketones. Tertiary alcohols resist oxidation.
  10. Esterification: Alcohols react with carboxylic acids in the presence of a catalyst (usually sulfuric acid) to form esters.

Important NEET Questions on Alcohols


1. Which of the following reagents can convert propanol to propanoic acid?

  1. Options: A. K2Cr2O7/H+, B. NaBH4, C. PCC, D. LiAlH4
  2. Answer: K2Cr2O7(Potassium dichromate in acidic medium)
  3. 2. What is the major product formed when 2-methyl-2-propanol is treated with concentrated H2SO4?
  4. Answer: 2-methylpropene (Dehydration reaction leading to alkene formation)

Section 2: Understanding Phenols

Phenols are aromatic compounds that contain a hydroxyl group directly bonded to an aromatic ring. They exhibit unique properties due to the conjugation between the hydroxyl group and the aromatic ring, leading to resonance.

Key Concepts and Reactions

1.Preparation of Phenols

  1. From Benzene Sulfonic Acid: Benzene is sulfonated to produce benzene sulfonic acid, which is then fused with sodium hydroxide to produce phenol.
  2. From Diazonium Salts: Phenols can be prepared from aromatic amines via diazotization followed by hydrolysis.
  3. 2. Physical Properties of Phenols
  4. Phenols generally have higher boiling points than alcohols of similar molecular weight due to stronger hydrogen bonding. Phenols are also slightly acidic due to the ability of the hydroxyl group to donate a proton.
  5. 3. Chemical Reactions of Phenols
  6. Electrophilic Substitution Reactions: Phenols undergo electrophilic substitution reactions more readily than benzene due to the electron-donating nature of the hydroxyl group. Common reactions include nitration, halogenation, and sulfonation.
  7. Oxidation: Phenol can be oxidized to form quinones, which are useful intermediates in various chemical reactions.
  8. Acidic Nature: Phenols are weak acids and can react with strong bases to form phenoxide ions.

Important NEET Questions on Phenols

1. Why is phenol more acidic than ethanol?

  1. Answer: Due to the resonance stabilization of the phenoxide ion formed after losing a proton, making the ion more stable than the ethoxide ion.
  2. 2. Which product is formed when phenol is treated with bromine water?
  3. Answer: 2,4,6-tribromophenol (Phenol undergoes electrophilic substitution readily with bromine, resulting in a tri-substituted product.)

Section 3: Understanding Ethers

Ethers are organic compounds that contain an oxygen atom bonded to two alkyl or aryl groups. They are classified as symmetrical or asymmetrical based on the nature of the substituents.

Key Concepts and Reactions

1. Preparation of Ethers

  1. Williamson Ether Synthesis: A popular method for preparing ethers, involving the reaction of an alkoxide ion with a primary alkyl halide via the SN2 mechanism.
  2. Dehydration of Alcohols: Ethers can also be formed by the dehydration of alcohols in the presence of an acid catalyst.
  3. 2. Physical Properties of Ethers
  4. Ethers generally have lower boiling points than alcohols due to the absence of hydrogen bonding. They are relatively non-polar and are used as solvents in organic reactions.
  5. 3. Chemical Reactions of Ethers
  6. Cleavage by Acids: Ethers can be cleaved by strong acids such as hydroiodic acid (HI) to form alkyl halides and alcohols.
  7. Autoxidation: Ethers can undergo slow oxidation in the presence of air to form peroxides, which are unstable and can be explosive.

Important NEET Questions on Ethers


1. Which of the following ethers can be prepared by Williamson’s synthesis?

  1. Options: A. CH3OCH3, B. C2H5OCH3, C. CH3OCH2C6H5
  2. Answer: All of these can be prepared by Williamson synthesis, but the reaction works best for primary alkyl halides.
  3. 2. What is the major product when diethyl ether reacts with concentrated HI?
  4. Answer: Ethyl iodide and ethanol (Ether cleavage by HI).

Section 4: Combined Concepts and Reactions

Understanding the interconnectedness of alcohols, phenols, and ethers can help students grasp the broader concepts of organic chemistry. For example:

1. Conversion Reactions: Being able to convert alcohols to ethers or phenols to quinones involves understanding the functional group interconversions that are frequently tested in NEET.

2. Comparative Analysis: Examining the acidity of phenol versus alcohols or the basicity of ethers can offer insights into the electronic effects of substituents and the nature of bonds.

Practice Questions for NEET Preparation


1. How will you convert ethanol to ethoxyethane?

  1. Answer: By using Williamson’s ether synthesis, treating ethanol with sodium to form sodium ethoxide, followed by reaction with ethyl iodide.
  2. 2. Why does phenol turn pink when exposed to air?
  3. Answer: Due to the formation of quinhydrone as phenol slowly oxidizes in air. 3. Arrange the following in the increasing order of their boiling points: ethanol, methanol, diethyl ether.
  4. Answer: Diethyl ether < Methanol < Ethanol (Considering the molecular weight and hydrogen bonding).

Conclusion

Mastering the concepts of alcohols, phenols, and ethers is vital for performing well in the NEET exam. By understanding their properties, reactions, and the mechanisms behind them, students can approach the questions with confidence. Regular practice with previous years’ questions, mock tests, and an in-depth study of reaction mechanisms will strengthen your preparation. Remember, thorough practice and understanding of these fundamental organic compounds are key to acing the NEET chemistry section.

study24x7
Write a comment...